The electronic and steric effects of neutral and ionic phosphines on Ir(I)-complex catalyzed hydroaminomethylation of olefins

Huan Liu,Da Yang,Yixuan Yao,Yongqiang Xu,Hongyan Shang,Xufeng Lin

Molecular Catalysis（2020）

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摘要

•Neutral and ionic phosphines with different electronic and steric effects.•Iridium-phosphines catalysed hydroaminomethylation of olefins.•Advantages of Ir-P catalyst for hydroaminomethylation over Rh-P system.•Characterization of Ir-H species by in situ high-pressure FT-IR spectroscopy.

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关键词

Hydroaminomethylation,Iridium catalyst,Neutral mono-phosphine,Green homogeneous catalysis

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