Pentafluoroethylaluminates: A Combined Synthetic, Spectroscopic, And Structural Study

Salts of the tetrakis(pentafluoroethyl)aluminate anion [Al(C2F5)(4)](-)were obtained from AlCl(3)and LiC2F5. They were isolated with different counter-cations and characterized by NMR and vibrational spectroscopy and mass spectrometry. Degradation of the [Al(C2F5)(4)](-)ion was found to proceed via 1,2-fluorine shifts and stepwise loss of CF(CF3) under formation of [(C2F5)(4-n)AlFn](-)(n=1-4) as assessed by NMR spectroscopy and mass spectrometry and supported by results of DFT calculations. In addition, the [(C2F5)AlF3](-)ion was structurally characterized.