Formation of the non-classical interhalide anion [I2Cl]- in methyl-bambus[6]uril cavity

Renato Salviato Cicolani,Antonio Gustavo Sampaio de Oliveira Filho,Ana Paula de Lima Batista,Grégoire Jean-François Demets

NEW JOURNAL OF CHEMISTRY（2020）

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摘要

Methyl-bambus[6]uril may form a variety of inclusion compounds, especially with anionic species. This communication reports the formation of the non-classical [I2Cl](-) interhalide ion when chloride-bearing methyl-bambus[6]uril interacts with iodine, both in solution and in the solid state.

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