Synthesis of 4-(4-Hydroxyaryl)-1,3-Dithiolium Perchlorates

Lucian Gabriel Bahrin,Catalin Neculai Lungu,Iuliean Vasile Asaftei,Ion Sandu

REVISTA DE CHIMIE（2019）

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摘要

4-(3,5-Dibromo-4-hydroxyphenyl)-2-(N, N-dialkylamino)-1,3-dithiol-2-ylium perchlorates have been synthesized by acid catalyzed cyclocondensation of 1-(3,5-dibromo-4-hydroxyphenyl)-1-oxaethan-2-yl dithiocarbamates. The latter compounds have been obtained from the reaction of the corresponding substituted w-bromoacetophenone with various salts of dithiocarbamic acids.

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关键词

acetophenones,charge-transfer,dithiocarbamates,1,3-dithiolium salts mesoionic compounds

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