Kinetic Investigation Of The Oxidation Of Sulphanilic Acid By Peroxomonophophoric Acid In Anionic Surfactant Sodium Lauryl Sulphate
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY(2003)
摘要
Oxidation of sulphanilic acid by peroxomonophosphoric acid (PMPA) in sulphuric acid medium is catalysed marginally in the presence of SLS. The rate reaches a maximum and then decreases. The oxidation rate-[micelle] profile is rationalised by Berezin model and binding constants of both the reactants with the micelle have been computed using the model.
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