Silica-supported Z-selective Ru olefin metathesis catalysts
Molecular Catalysis(2020)
摘要
•Synthesis of a mesostructured hybrid silica material containing bulky thiol groups.•Immobilization of Ru-alkylidene complexes via a chlorine to thiol exchange.•Development of the first Z-selective olefin metathesis catalysts.•Activity and stereoselectivity comparable to that obtained with the homogeneous versions.
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关键词
Olefin metathesis,Z-selectivity,Ruthenium,NHC,Supported complexes
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