Chemical preparation, crystal structure, Hirshfeld surface analysis, spectroscopy, DFT studies, thermal decomposition and magnetic measurements of (C4H12N2)[FeCl3(H2O)3]Cl2

Ines Kadri,Slim Elleuch,Carlos Jose Tavares,Manuel Bañobre-López,Michel François,Walid Rekik

Inorganic Chemistry Communications（2020）

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摘要

•The 0D hybrid material (C4H12N2)[FeCl3(H2O)3]Cl2 crystallizes in P21/m space group.•Spectroscopic analyses verified the presence of both organic and inorganic groups.•The thermal decomposition of the compound leads to the iron oxide as final product.•The magnetic measurements showed antiferromagnetic interactions at lower temperature.

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关键词

H-bonded structure,Vibrational spectroscopy,Thermal decomposition,Magnetic properties

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