Mechanistic study on the conversion of d-fructose into deoxyfructosazine: Insights from NMR and DFT study

Lingyu Jia,Yan Qiao,Christian Marcus Pedersen,Shiyu Jia,Hui Ma,Zhenzhou Zhang,Yingxiong Wang,Xianglin Hou

Chemical Engineering Science（2020）

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摘要

In situ NMR, selective 1D TOCSY spectra and DFT have been used for analyzing reactive intermediates in fructose reactions, where fructose with diammonium hydrogen phosphate [(NH4)2HPO4] is consumed via a glucosamine intermediate (GlcNH2) which is subsequently converted into deoxyfrutosazine (2,5-DOF).

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关键词

Fructose,C−N bond construction,NMR techniques,DFT calculation,Reactive intermediate,Deoxyfructosazine

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