Phase equilibria of tetra-iso-amyl ammonium bromide (TiAAB) semiclathrates with CO2, N2, or CO2 + N2

Soyoung Kim,Gyeol Ko,Ki-Sub Kim,Yongwon Seo

The Journal of Chemical Thermodynamics（2020）

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摘要

•We measure phase equilibria of TiAAB semiclathrates with CO2, N2, or CO2 + N2.•We employ an isochoric method and a stepwise DSC method for phase equilibria.•TiAAB semiclathrates with guest gases form at lowered p and elevated T.•Raman spectroscopy confirms the inclusion of CO2 and N2 in TiAAB semiclathrates.

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关键词

CO2,N2,Flue gas,Tetra-iso-amyl ammonium bromide,Semiclathrate

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