Separation of Spin and Charge Transport in Pristine π-Conjugated Polymers.

We have experimentally tested whether spin-transport and charge-transport in pristine pi-conjugated polymer films at room temperature occur via the same electronic processes. We have obtained the spin diffusion coefficient of several pi-conjugated polymer films from the spin diffusion length measured by the technique of inverse spin Hall effect and the spin relaxation time measured by pulsed electrically detected magnetic resonance spectroscopy. The charge diffusion coefficient was obtained from the time-of-flight mobility measurements on the same films. We found that the spin diffusion coefficient is larger than the charge diffusion coefficient by about 1-2 orders of magnitude and conclude that spin and charge transports in disordered polymer films occur through different electronic processes.