New insights into the electrochemical conversion of CO2 to oxalate at stainless steel 304L cathode

Journal of CO2 Utilization(2020)

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摘要
•Zinc oxalate synthesized in a batch reactor at 2 bar pressure with an average Faradaic efficiency of 73.9%.•Pure oxalic acid extracted from zinc oxalate with 58.2 % efficiency using ester hydrolysis process.•Low water content in the electrolyte solution ∼37 ppm and optimised current density of 15 mA/cm2 enhances oxalate formation.
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关键词
Carbon dioxide,Electroreduction,Oxalic acid,SS 304L alloy,Sacrificial anode
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