Diastereoselective 2, 3-diazidation of indoles via copper(II)-catalyzed dearomatization

Jiang Liu, Zhongjin Fang,Xin Liu,Yandong Dou,Jianze Jiang,Fangfang Zhang,Jiaojiao Qu,Qing Zhu

Chinese Chemical Letters（2020）

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摘要

The copper-catalyzed directed dearomatization of indoles with the assistance of directing groups has been developed, which makes the synthesis of 2,3-diazido indolines with good yields and excellent diastereoselectivities in aqueous solution.

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关键词

Indole,Diastereoselective,Dearomatization,2,3-Diazidation,Indoline

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