Artificial porous structure: An effective method to improve thermoelectric performance of Bi2Te3 based alloys

Introduction of porous structure is a feasible and promising method for improving thermoelectric performances for thermoelectric materials. Meanwhile, the uniformity of pores distribution plays a decisive role in the objective evaluation of thermoelectric properties for porous structures. In this work, extremely uniform porous structures in p-type Bi0.4Sb1.6Te3 bulks were obtained by pre-mixing with NH4HCO3 combined with resistance pressing sintering (RPS) process. The thermoelectric performance was obviously affected by the porous structure. The increasing porosity resulted in a significant decrease in electrical and thermal conductivity. It was inspiring that the reduction of thermal conductivity could compensate for the deterioration of electrical conductivity, leading to the enhancement in ZT value. The maximum ZT value of 1.11 was obtained for the sample prepared by pre-mixing with 5 ​wt % NH4HCO3 at 343 ​K, which was 20% higher than that of the fully dense sample. Finally, the advantages on the homogeneity of pores, thermoelectric properties and mechanical properties of the sample prepared by this method are confirmed through comparing with the sample prepared without NH4HCO3, when their relative densities both are 90%.