Colloidal Syntheses Of Zero-Dimensional Cs4snx6 (X = Br, I) Nanocrystals With High Emission Efficiencies

Li Tan,Wu Wang,Qian Li,Zhishan Luo,Chao Zou,Min Tang,Liming Zhang,Jiaqing He,Zewei Quan

CHEMICAL COMMUNICATIONS（2020）

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摘要

Phase-pure all-inorganic zero-dimensional (0D) tin halide Cs4SnX6 (X = Br, I) nanocrystals (NCs) are successfully prepared for the first time. The as-prepared Cs4SnBr6 NCs exhibit a strongly Stokes-shifted broadband emission with a high photoluminescence quantum yield (PLQY) of 21% at room temperature.

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