Synthesis of the ABCD fragment of gymnocin-B

Takeo Sakai, Kohei Hata, Yuki Kitamura, Renji Ishibashi,Yuji Mori

Tetrahedron Letters（2019）

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摘要

•Synthetic study of naturally occurred pentadecacyclic ether gymnocin-B.•Convergent synthesis of the ABCD fragment of gymnocin-B is accomplished using the oxiranyl anion strategy.•The five-membered A ring is constructed via a stereoselective radical cyclization of a neopentyl-type iodide.

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关键词

Marine natural product,Gymnocin-B,Polycyclic ether,Oxiranyl anion

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