Preparation and calibration of a 231 Pa reference material

A 231 Pa reference material has been characterized for amount of protactinium. This reference material is primarily intended for calibration of 233 Pa tracers produced for 235 U– 231 Pa model age measurements associated with nuclear forensics and nuclear safeguards. Primary measurements for characterization were made by isotope dilution mass spectrometry of a purified 231 Pa solution using a 233 Pa isotopic spike. The spike was calibrated by allowing multiple aliquots of the 233 Pa spike solution to decay to 233 U and then measuring the ingrown 233 U by isotope dilution mass spectrometry using a certified uranium assay and isotopic standard as a reverse-spike. The new 231 Pa reference material will simplify calibration of the 233 Pa isotope dilution spikes, provide metrological traceability, and potentially reduce the overall measurement uncertainty of model ages.