Regeneration of Washing Effluents for Remediation of Petroleum-Hydrocarbons-Contaminated Soil by Corncob-Based Biomass Materials.

Surfactant-enhanced soil washing is an effective remediation method for petroleum-hydrocarbons-contaminated soil. The residual petroleum hydrocarbons in the washing effluents reduce the elution ability of the washing effluents and cause secondary pollution to the environment. In this work, modified corncobs were prepared and used as selective adsorbents to remove the residual petroleum hydrocarbons in washing effluents. The structure of adsorbent was characterized and the adsorption conditions were optimized. With the adsorption by corncob-based adsorbents, washing effluents can be regenerated and recycled. After five cycles, the recovery efficiency of the washing effluents is still as high as 75.4%. The optimal adsorbent linear alkylbenzene sulfonates (LAS-Cb) also exhibited excellent recyclability, which can be recycled five times. The selective adsorption mechanism of the LAS-Cb for petroleum hydrocarbons in washing effluents, related to its huge hydrophobic core and surface electronegativity, is proposed.