Photodissociation dynamics of dichlorodifluoromethane (CF2Cl2) around 235 nm using time-sliced velocity map imaging technology
CHINESE JOURNAL OF CHEMICAL PHYSICS(2019)
摘要
Photodissociation dynamics of dichlorodifluoromethane (CF2Cl2) around 235 nm has been studied using the time-sliced velocity map imaging technology in combination with the resonance enhanced multi-photon ionization technology. By measuring the raw images of chlorine atoms which are formed via one-photon dissociation of CF2Cl2, the speed and angular distributions can be directly obtained. The speed distribution of excited-state chlorine atoms consists of high translation energy (ET) and low ET components, which are related to direct dissociation on (3)Q(0) state and predissociation on the ground state induced by internal conversion, respectively. The speed distribution of ground-state chlorine atoms also consists of high ET and low ET components which are related to predissociation between (3)Q(0) and (1)Q(1) states and predissociation on the ground state induced by internal conversion, respectively. Radical dissociation channel is confirmed, nevertheless, secondary dissociation and three-body dissociation channels are excluded.
更多查看译文
关键词
Dichlorodifluoromethane,Time-sliced velocity map imaging technology,Internal conversion
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络