ONO pincer type ligand complexes of Al(III) as efficient catalyst for chemical fixation of CO2 to epoxides at atmospheric pressure

Journal of Catalysis(2019)

引用 33|浏览12
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摘要
•Hydrazone-based ONO pincer mono-nuclear Al complexes were synthesized and characterized.•These ONO-pincer Al-complexes are excellent catalyst for the fixation of CO2.•The coupling was catalyzed at atmospheric pressure with the highest conversion.•For the mechanistic investigation intermediate species were detected.
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关键词
CO2 fixation,Pincer ligand,Aluminium complexes,Cyclic carbonate,Homogeneous catalysis
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