A new quasi-one-dimensional compound Ba 3 TiTe 5 and superconductivity induced by pressure

We report systematic studies of a new quasi-one-dimensional (quasi-1D) compound, Ba 3 TiTe 5 , and the high-pressure induced superconductivity therein. Ba 3 TiTe 5 was synthesized at high pressure and high temperature. It crystallizes into a hexagonal structure ( P 6 3 /mcm ), which consists of infinite face-sharing octahedral TiTe 6 chains and Te chains along the c axis, exhibiting a strong 1D characteristic structure. The first-principles calculations demonstrate that Ba 3 TiTe 5 is a well-defined 1D conductor; thus, it can be considered a starting point to explore the exotic physics induced by pressure by enhancing the interchain hopping to move the 1D conductor to a high-dimensional metal. For Ba 3 TiTe 5 , high-pressure techniques were employed to study the emerging physics dependent on interchain hopping, such as the Umklapp scattering effect, spin/charge density wave (SDW/CDW), superconductivity and non-Fermi liquid behavior. Finally, a complete phase diagram was plotted. The superconductivity emerges at 8.8 GPa, near which the Umklapp gap is mostly suppressed. T c is enhanced and reaches a maximum of ~6 K at ~36.7 GPa, where the SDW/CDW is completely suppressed, and a non-Fermi liquid behavior appears. Our results suggest that the appearance of superconductivity is associated with the fluctuation due to the suppression of the Umklapp gap and that the enhancement of the T c is related to the fluctuation of the SDW/CDW.