Molecular di- and tetra-nuclear zinc(II) phosphates with sterically hindered aryl phosphate mono esters ligands

Biswajit Santra,Vierandra Kumar,Pankaj Kalita,Vivek Gupta,Debdeep Mandal,Amitava Chandra,Mayank Joshi,Angshuman Roy Choudhury,Anukul Jana,Vadapalli Chandrasekhar

Polyhedron（2019）

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摘要

Di- and tetranuclear Zn(II) phosphates were prepared in the reactions of zinc(II) acetate and bulky aryl phosphate ligands in the presence of suitable co-ligands such as 1,10-phenanthroine or pyrazole. Use of a linear co-ligand, 4,4′-bipyridine afforded a one-dimensional coordination polymer.

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关键词

Bulky aryl phosphate,Dinuclear Zn(II)-phosphate,Anionic Zn(II)-phosphate,Tetranuclear D4R Zn(II),1-D polymeric Zn(II)-phosphate

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