Synthesis, crystal structure and reactivity of homobimetallic vanadium(V) complexes derived from oxaloyldihydrazone ligands

Ibanphylla Syiemlieh,Mrityunjaya Asthana,Sunshine D. Kurbah,Ram A. Lal

Polyhedron（2019）

引用 13|浏览6

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摘要

The reaction of disalicyaldehydeoxaloyldihydrazone with vanadium pentoxide in methanol yields the vanadium(V) complex [(CH3)2NH2]2[(VO2)2(slox)]·2H2O, which oxidizes alcohols to aldehydes and ketones with H2O2 as the terminal oxidant.

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关键词

Dihydrazone,Dinuclear vanadium complex,Aldehyde,Ketones,Oxidative bromination

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