Post-synthetic modification of a Tb-based metal–organic framework for highly selective and sensitive detection of metal ions in aqueous solution
NEW JOURNAL OF CHEMISTRY(2019)
摘要
Post-modification of a hydroxyl-enriched metal-organic framework (MOF) with acryloyl chloride afforded the modified material Tb-HIAAC with acrylate groups. Tb-HIAAC significantly boosted the selectivity and sensitivity of the fluorescence response to Fe3+ compared with the original compound, its LOD being only 70 nM for Fe3+ ions. Furthermore, a test paper was easily prepared, and its response to Fe3+ ions was visible to the naked eye.
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关键词
metal–organic ions,metal–organic framework,aqueous solution,post-synthetic,tb-based
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