Zeolite Nanocrystals Protect the Performance of Organic Additives and Adsorb Acid Compounds during Lubricants Oxidation.

Zeolite nanocrystals were used as proactive agents to extend the lifetime of commercial lubricants by protecting the performance additives from depletion and adsorbing the acid formed during oxidation. The nanosized zeolites were introduced into four lubricants and subjected to oxidation (90 degrees C and 150 degrees C). A strong affinity towards protection of zinc dialkyldithiophosphate (ZDDP) additive was demonstrated by P-31 NMR (nuclear magnetic resonance) and FTIR (fourier-transform infrared) spectroscopy even after heating at 150 degrees C for 24 h. FTIR profiles of lubricants aged in the presence of LTL (Linde Type L zeolite) showed lower oxidation degree while the formed oxidation products (aldehydes, ketones, and acids) were adsorbed on the zeolite crystals acting as scavengers.