Single-handed supramolecular double helix of homochiral bis(N-amidothiourea) supported by double crossed C-I···S halogen bonds

Kunshan Zou
Kunshan Zou
Jinlian Cao
Jinlian Cao
Xiaorui Li
Xiaorui Li
Zhixing Zhao
Zhixing Zhao
Wanzhen Liang
Wanzhen Liang

Nature communications, pp. 3610-10, 2019.

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Abstract:

The natural DNA double helix consists of two strands of nucleotides that are held together by multiple hydrogen bonds. Here we propose to build an artificial double helix from fragments of two strands connected by covalent linkages therein, but with halogen bonding as the driving force for self-assembling the fragments to the double helix...More

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