Magneto-structural Studies of Two M-O-M Bridged Homochiral Mixed Valence Co(II)/Co(III) Complexes

Amy Trinh Pham,Parisa Abbasi,Gabriele Delle Monache,Eleni C. Mazarakioti,Jeremy M. Rawson,Theocharis C. Stamatatos,Melanie Pilkington

Polyhedron（2019）

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摘要

Two homochiral M–O–M bridged mixed valence complexes [CoIII2CoII(mpm)6]·(ClO4)2 (1) and [CoII2CoIII2(μ3-OMe)2(μ-mpm)4(NO3)2(MeO)2] (2) with linear and defect dicubane topologies respectively were prepared and characterized from the reaction of R- and S-mpmH (where mpmH = -methyl-2- pyridinemethanol) with an appropriate Co(II) salt.

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关键词

α-Methyl-2-pyridinemethanol,Defect dicubane,Homochiral,Mixed valence clusters,3d Clusters

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