Crystal structure of 1-hepta­fluoro­tolyl-closo-1,2-dicarbadodeca­borane

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS(2019)

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摘要
The mol­ecular structure of the title compound 1-(2′,3′,5′,6′-tetra­fluoro-4′-trifluoro­methyl­phen­yl)-closo-1,2-dicarbadodeca­borane, C9H11B10F7, features an intra­molecular ortho-F⋯H2 hydrogen bond [2.11 (2) Å], which is responsible for an orientation of the hepta­fluoro­tolyl substituent in which the plane of the aryl ring nearly eclipses the C1—C2 cage connectivity.
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关键词
crystal structure,carborane,intramolecular F center dot center dot center dot H hydrogen-bond
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