Rutile RuO2 dispersion on rutile and anatase TiO2 supports: The effects of support crystalline phase structure on the dispersion behaviors of the supported metal oxides

Catalysis Today(2020)

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摘要
•Rutile RuO2 disperses better on rutile r-TiO2 than on anatase a-TiO2 support.•RuO2 has thus a stronger interaction with r-TiO2 than with a-TiO2 support.•RuO2/r-TiO2 owns richer facile oxygen sites and higher reactivity than RuO2/a-TiO2.•Support crystalline structures influence the dispersion of supported metal oxides.•A like-disperses-like rule is proposed for the supported metal oxide systems.
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关键词
Support crystalline phase effect,Rutile and anatase TiO2 supports,RuO2/TiO2 catalysts,CO oxidation,Like-disperses-like phenomenon
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