Cucurbituril-Based Reusable Nanocomposites for Efficient Molecular Encapsulation

ACS Sustainable Chemistry & Engineering(2019)

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摘要
Cucurbituril (CB) has recently been employed in many fields, including water purification, solar cells, energy conversion, and biomedical engineering. However, the poor solubility of CB poses a serious obstacle to the further development of CB applications. To enhance the solubility of members of the CB family (CB[5–8]) by preventing self-aggregation in aqueous solutions, the synthesis of highly stable, rapid, and water-dispersible particles is presented in this paper based on a simple process that employs a nanocomposite composed of CB and amine-modified diatomaceous earth (DA). CB can be coated onto the surface of the DA and stabilized to produce a novel material that is useful for various applications. The nanocomposite (CB-DA) exhibited a strong host–guest interaction, exhibiting a more than 100-fold increase in efficiency and greater stability in dye and pathogen encapsulation as a result of the host–guest interaction, electrostatic interaction, and covalent bonding. We applied CB-DA to a commerciali...
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关键词
Supermolecule,Biosilica,Nanocomposite,Rapid absorbance,Recycle,Molecular encapsulation
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