Highly active Mn(III) meso-tetrakis(2,3-dichlorophenyl)porphyrin catalysts for the cycloaddition of CO2 with epoxides

Jorge Luiz Sônego Milani,Alexandre Moreira Meireles,Bruno Noschang Cabral, Werberson de Almeida Bezerra,Felipe Terra Martins,Dayse Carvalho da Silva Martins,Rafael Pavão das Chagas

Journal of CO2 Utilization（2019）

引用 34|浏览7

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摘要

•New class of MnIII-porphyrin catalysts.•Highly active catalytic system for the cycloaddition reaction of CO2 with epoxides.•Excellent conversions, TONs and TOFs in the synthesis of cyclic carbonates.•Recyclable catalytic system.

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关键词

Carbon dioxide,Cyclic carbonate,Metalloporphyrins,Manganese complexes,Homogeneous catalysis

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