Supramolecular catalysis based on discrete heterometallic coordination-driven metallacycles and metallacages

Coordination Chemistry Reviews（2019）

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摘要

•A focus on the recent developments of supramolecular catalysis based on HCCs.•Metalloligand and self-sorting approaches are commonly used to construct HCCs.•Instances of catalytic macrocyclic or cage-like HCCs are discussed in detail.

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关键词

acac,BArF,BINOL,BRs,CoTPyP,Cp,Cp*,DABCO,DFT,ee,GS,HCCs,ILCT,LMCT,M(TPyP),MLCT,Mn(TPyP)(Cl),MOFs,NAI,OKR,Opba,Phen,ppba,PPNCl,Py,salen,TAPP,TBSC,x-PC,ZnTPP

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