Defining the origins of multiple emission/excitation in rhenium-bisthiazole complexes

Nicholas Azzarelli,Shashikanth Ponnala,Alexander Aguirre,Sara J. Dampf,Margaret P. Davis,Michael T. Ruggiero, Valerie Lopez Diaz,John W. Babich,Michael Coogan,Timothy Korter,Robert P. Doyle,Jon Zubieta

Inorganica Chimica Acta（2019）

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摘要

The unusual luminescence behavior of {Re(CO)3}+1-core/thiazole complexes of the type exemplified by the cationic [Re(CO)3{(C3H2SNCH2)2N(CH2)4NH3}]+2 shown above was investigated by fluorescence spectroscopy, x-ray diffraction, DFT calculations and solid state luminescence studies. The relative emission intensities of [Re(CO)3{(C3H2SNCH2)2N(CH2)4NH3}]Br2 (4-BT·HBr) as a 2D grid of excitation vs. emission wavelength are displayed on the contour map.

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关键词

Rhenium tricarbonyl,Thiazole ligands,Fluorescence,Kasha-Vavilov Rule,Solid state fluorescence,X-ray crystallography,DFT

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