Regioselectivity in C–H activation: Reactions of N-heterocyclic indenes with Ru3(CO)12

Polyhedron（2019）

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摘要

Reaction of 2-methyl-3-(6-ethyl-2-pyridyl)indene with Ru3(CO)12 generated a six-membered cycloruthenated dinuclear complex {(C2H5C5H4N)(μ2-η5,η1-C9H5CH2)}Ru2(CO)5 (2) via regioselective C(sp3)−H bond activation.

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关键词

Cycloruthenium,Regioselectivity,CH activation,Indenyl,Cluster

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