Construct 3D Pd@MoS2-conjugated polypyrrole framworks Heterojunction with unprecedented photocatalytic activity for Tsuji-Trost reaction under visible light

We report a simple technique for forming 3D Pd@MoS2-conjugated polypyrrole framworks (Pd@MoS2CPFs) and first demonstrated that the Tsuji-Trost reaction using Pd@MoS2CPFs photocatalyst could be realized under visible light at room temperature. More importantly, we reported the synergistic photocatalysis by the electron–hole pairs and Pd NPs in Mott–Schottky junction system for the acceleration of the Tsuji-Trost reaction, which is further confirmed by DFT calculations.