Pd-catalyzed alkoxycarbonylation of alkenes promoted by H2O free of auxiliary acid additive

Molecular Catalysis(2020)

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摘要
•Efficient Pd-catalyzed alkoxycarbonylation of alkenes with H2O as promotor.•Formation and stability of PdH active species detected by in situ high pressure FT-IR spectroscopy.•Ligand effect of Xantphos on alkoxycarbonylation of alkenes.
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关键词
Alkoxycarbonylation,Palladium hydride,In situ FT-IR analysis
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