Palladium complexes bearing κ2-N,N and κ3-N,N,O pendant amine bis(phenolate) ligands

Brendan J. Graziano,Eric M. Collins,Nathaniel C. McCutcheon, Claire L. Griffith,Nicole M. Braunscheidel,Trilisa M. Perrine,Bradley M. Wile

Inorganica Chimica Acta（2019）

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摘要

•Pendant donors generate Pd complexes that are distinct from bridging donors.•Bulky amine bis(phenolate) ligands form coordinatively less saturated Pd complexes.•Computational studies suggest a bulky para substituent may direct complex behavior.

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关键词

Palladium,X-ray,NMR,Anagostic

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