Synthesis, crystal structure and MMCT of a heterobimetallic cyanide-bridged complex trans-BrRuII(dppe)2(μ-CN)(FeIIIBr3)

Polyhedron（2018）

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摘要

A heterobimetallic cyanide-bridged complex trans-BrRuII(dppe)2(μ-CN)(FeIIIBr3) (2) and its parent trans-ClRuII(dppe)2(CN) (1) were synthesized and characterized. The crystal structural data, MMCT and EPR spectra indicate the existence of some electron delocalization along FeIIINCRuII in complex 2.

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关键词

Cyanide-bridged,Magnetic properties,Crystal structure,MMCT,Designed and synthesized

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