Phase Structure Transformations and Electrical Properties of (Na0.52K0.4425)(Nb0.8925Sb0.07)O3–0.0375LiTaO3 Ceramics According to Sintering Temperature
ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY(2018)
摘要
In the present work, the effects of sintering temperature are investigated for the lead-free (Na0.52K0.4425)(Nb0.8925Sb0.07)O-3-0.0375LiTaO(3) ceramics. The phase structure transformations are identified via the XRD patterns and Rietveld refinement method. In addition, the electric properties are investigated through the empirical law, the Curie-Weiss law and the ferroelectric hysteresis loops. The best piezoelectric properties (P-r = 41.96 mu C/cm(2), E-c = 7.77 kV/cm, d(33) = 310 pC/N and k(P) = 48%) were obtained at the sintering temperature of 1130 degrees C. The response mechanisms suggest that a more polymorphic phase boundary, a more uniform grain, a higher density and fewer cation-oxygen vacancies can improve the electric properties. (C) 2018 The Electrochemical Society.
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