Preparation and Characterization of a µ-P2O7-µ-HPO4 Dinuclear Fe2(III, III) Complex

Yuji Miyazato,Kouta Imaizumi,Rikako Tanaka,Tohru Wada,Nobuyuki Matsushita

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN（2018）

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摘要

The [{Fe(Me(3)tacn)}(2)(mu-P2O7)(mu-HPO4)]center dot 12H(2)O dinuclear Fe-2(III, III) complex was prepared. The HPO42- bridge in the complex arises from hydrolysis of the pyrophosphate bound to the Fe(III) centers in the trinuclear [{Fe(Me(3)tacn)}(3)-(P2O7)(2)](+) intermediate. Electrochemical reduction of this complex at pH < 3.2 results in dissociation of the H2PO4 bridge.

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关键词

Dinuclear Fe-2 complex,Pyrophosphate,Hydrogen phosphate

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