Through-conjugation of two phosphaalkyne (‘CP’) moieties mediated by a bimetallic scaffold

Dalton Transactions（2018）

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摘要

The bis-cyaphide complex [{Ru(dppe)2}2{μ-(CC)2C6H4-p}(CP)2] is the first molecule to incorporate two phosphaalkyne ‘CP’ moieties within a through-conjugated scaffold, and demonstrates interesting redox behaviour.

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