Highly selective fluorescent probe for switch-on Al3+ detection and switch-off F− detection

Journal of Photochemistry and Photobiology A: Chemistry(2018)

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摘要
•A highly selective Al3+ probe (1) was synthesized and investigated.•Al3+ was detected via “switch on” complexation by hemiacetal 2 formed from 1 in MeOH.•In situ generated 2-Al3+ detected F− through a “switch off” response.•The fluorescence mechanism of 1 was explained by combined ESIPT and CHEF effects.•Sequential detection of Al3+ and F− was achieved.
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关键词
Fluorescent probe,Hemiacetal,Aluminum ion selectivity,Fluoride,ESIPT,CHEF
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