Tf2NH-Catalyzed 1,6-Conjugate Addition of Vinyl Azides with p-Quinone Methides: A Mild and Efficient Method for the Synthesis of β-Bis-Arylamides

Jayant Rathod,Brijesh M. Sharma,Pramod S. Mali,Pradeep Kumar

SYNTHESIS-STUTTGART（2017）

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摘要

Tf2NH-catalyzed tandem 1,6-conjugate addition/Schmidt type rearrangement using vinyl azides and p-quinone methides to access a variety of beta-bis-arylated amides is reported. The method is quick, efficient, mild, and high yielding with broad substrate scope.

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关键词

vinyl azide,p-quinone methide,Bronsted acid,1,6-conjugate addition,rearrangement,beta-bis-arylamides

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