Combined poisoning effect of K+ and its counter-ion (Cl− or NO3−) on MnOx/TiO2 catalyst during the low temperature NH3-SCR of NO

Chemical Engineering Journal(2017)

引用 33|浏览11
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摘要
•Alkali poisoning is a major concern for low-T NH3-SCR on MnOx/TiO2.•KCl impacts more severely than KNO3 on deNOx activity due to combined poisoning effects.•K+ poisons strong Lewis acid sites of the catalyst regardless of counter-ion.•Cl− inhibits oxygen availability from MnOx.•NO3− strongly affects process selectivity for T>150°C.
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关键词
Alkali poisoning,SCR,Marine diesel,TPD,NH3,MnOx
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