Efficient Synthesis And Raft Polymerization Of The Previously Elusive N-[(Cycloalkylamino)Methyl]Acrylamide Monomer Class

Schiff base salts allowed the multigram preparation of methylene amino substituted acrylamide monomers. These, as well as the hydrochloride salt intermediates, were subjected to controlled/living polymerizations for the first time. One-pot sequential reversible addition-fragmentation chain transfer (RAFT) polymerizations resulted in well-defined di- and triblock copolymers. Additional Supporting Information may be found in the online version of this article. Supporting Information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.