Synthesis, optical properties and stability of two σ-π conjugated polycarbosilanes with silylene-1,2-diphenyleneethylene-silylene and silylene-terephthalyidene-silylene backbones via Grignard reactions

Fen Chen,Rui Zhou,Liang Liao,Ru Jia, Rong Zhao,Changping Fu,Rongqian Yao,Zude Feng

Synthetic Metals（2016）

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摘要

PCS-SDS products with diphenyl and CC synthesized via Grignard reactions possess extended σ-π conjugation and exhibit strong emission intensity, high quantum yield, long fluorescence lifetime, excellent oxidation, UV and thermal shock resistance.

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关键词

Polycarbosilane,Diphenyl,Photoluminescence,σ-π conjugation,Oxidation cross-linking,Ultraviolet radiation

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