Six-membered cyclopalladated N , N ′, N ″-triarylguanidines, [{ κ 2 ( C , N )Pd} 2 ( μ- OAc)( μ -Pz)], [ κ 2 ( C , N )Pd( μ- Pz)] 2 and a novel [AgNO 3 ⊂{{ κ 2 ( C , N )Pd} 2 ( μ- NO 3 )( μ -Pz)}]: Syntheses, reactivity studies, structural aspects, and solution behavior

Pallavi Agarwal,Jisha Mary Thomas,Chinnappan Sivasankar,Munirathinam Nethaji,Natesan Thirupathi

Polyhedron（2016）

引用 9|浏览2

暂无评分

摘要

Cyclopalladated N,N′,N″-tri(2-tolyl)guanidine, 6 encapsulates AgNO3 inside a cavity to afford complex 12 due to stabilization attained through Pd→Ag (d8→d10) and Ag-η1arene (soft–soft) interactions.

查看译文

关键词

Pyrazoles,Conformers,Fluxional behavior,Palladium–silver complex,Guanidine

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要