Meridane and uladane, two unprecedented sesquiterpene skeletons obtained by Wagner–Meerwein rearrangements of Longipinane derivatives

Pablo A. Chacón-Morales,Juan M. Amaro-Luis

Tetrahedron Letters（2016）

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摘要

•7β,9α-Dihydroxylongipin-2-en-1-one (1) was obtained from Stevia lucida Lagasca.•Two compounds with an unprecedented carbocyclic skeleton were obtained from (1).•Mechanisms based on Wagner–Meerwein rearrangements are proposed.

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关键词

Longipinane,Molecular rearrangements,Novel skeletons,NMR,Stevia lucida Lagasca

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