VOx-Nb/La-γAl2O3 catalysts for oxidative dehydrogenation of ethane to ethylene

Journal of the Taiwan Institute of Chemical Engineers(2016)

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摘要
•VOx-Nb/La-γAl2O3 catalyst for gas phase oxygen free ODH of ethane.•La stabilized the γAl2O3 in high temperature reduction/oxidation cycles.•Nb isolated VOx on La-γAl2O3 and minimizes crystalline V2O5 formation.•Achieved high ethylene selectivity in gas phase oxygen free conditions.
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关键词
Oxidative dehydrogenation,Fluidized-bed,Oxygen-free environment,TPD modeling,Ethane conversion,Ethylene selectivity
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