Synthesis and Optical Properties of 1,4- and 1,2-Dicyanodibenzodioxins Possessing Donor–π-Acceptor Architecture
SYNLETT(2016)
摘要
The synthesis and photophysical characterization of isomeric 1,4-and 1,2-dicyanodibenzodioxins is reported. The molecules exhibit optical spectra in the visible region and possess large (ca. 100 nm) Stokes shifts. The synthetic protocol is simple and high-yielding and the presence of replaceable fluorine atoms on the activated dibenzodioxin moiety provides the opportunity for further transformation towards molecules bearing push–pull architecture.
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