Synthesis and structural features of new pentacoordinated monofluorosilanes containing C,O-chelate ligands based on 2-amino acid N -methylamides

Russian Chemical Bulletin(2018)

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摘要
Pentacoordinated monofluorosilanes R 1 SO 2 NHCHR 2 C(O)N(Me)CH 2 SiMe 2 F containing moieties of N′ -methyl- N -(organosulfonyl)-2-amino acid amides of glycine, alanine, and leucine as C,O-chelating ligands were synthesized via the reaction of corresponding disiloxanes with BF 3 •Et 2 O. The structures of obtained compounds were investigated by single-crystal X-ray diffraction analysis.
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关键词
silicon-containing amino acids,pentacoordinated silicon compounds,syn thesis,X-ray diffraction analysis
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